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Huizhang Liu, Nuno A. G. Bandeira, Vitor Félix and Maria José Calhorda Tris(organotin)tungstogermanate, a Sandwich Organometallic Derivative of a Keggin-Type Polyoxometalate: Synthesis and DFT Study European Journal of Inorganic Chemistry 2013

Version of Record online: 7 FEB 2013 | DOI: 10.1002/ejic.201201385

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The [(C6H5SnOH)3(α-GeW9O34)2]14– anion is the first polyoxometalate based on two Keggin ions that contain germanium, which are bridged by three phenyltin groups. The threefold symmetry is reflected in the arrangement of the three OH groups trans to the phenyl groups in the tin fragment engaged in hydrogen bonding in the plane between the Keggin ions.

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