Salvador Cardona-Serra, Juan Modesto Clemente-Juan, Eugenio Coronado, Carlos Martí-Gastaldo and Efrén Navarro-Moratalla The Use of Polyoxometalates in the Design of Layer-Like Hybrid Salts Containing Cationic Mn4 Single-Molecule Magnets European Journal of Inorganic Chemistry 2013
Polyoxometalates (POMs) permit the controlled organization of single-molecule-magnet (SMM) units within the layered architecture of hybrid ionic crystals. By taking Mn4 (complex cluster) as a case study, the use of POMs with different sizes and charges yields differently packed structures. The slow relaxation properties of the SMM component are strongly affected by the counteranion employed.
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