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Hai-Kuan Yang, Ming-Ming Su, Li-Jun Ren, Jing Tang, Yu-Kun Yan, Wen-Ke Miao, Ping Zheng and Wei Wang Post-Functionalization of an Anderson-Type Polyoxomolybdate Using a Metal-Free Diels–Alder Click Reaction European Journal of Inorganic Chemistry 2013

Version of Record online: 14 JAN 2013 | DOI: 10.1002/ejic.201201399

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Diels–Alder (DA) click chemistry is an efficient post-functionalization method for organic-modified polyoxomolybdates. The DA reaction can be carried out under mild conditions, with high yields and without the use of any additives or catalysts; it provides easy access to a new class of complex polyoxometalate–organic hybrids with novel architecture or value-added functionalities.

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