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Roger Persson, Marc J. Stchedroff, Roberto Gobetto, Carl J. Carrano, Michael G. Richmond, Magda Monari and Ebbe Nordlander Synthesis, Characterization, and Dynamic Behaviour of Triosmium Clusters Containing the Tridentate Ligand {Ph2PCH2CH2}2S (PSP) European Journal of Inorganic Chemistry 2013

Article first published online: 1 MAR 2013 | DOI: 10.1002/ejic.201201403

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New clusters coordinated by the tridentate ligand {Ph2PCH2CH2}2S have been synthesised and structurally characterised. A new example of a nondestructive rearrangement of a P,S-bridged triosmium cluster that involves a sulfur carbonyl exchange route is reported.

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