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Richard S. Herrick, Christopher J. Ziegler, Kathryn L. Kennedy, Calvin Luu and James T. Engle Synthesis of C2-Symmetric Dimeric ReI Peptide Complexes European Journal of Inorganic Chemistry 2013

Version of Record online: 6 FEB 2013 | DOI: 10.1002/ejic.201201444

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Gly-Gly-OH and Gly-Ala-OH each react with Re(CO)3+ to produce [Re(CO)3(Gly-Xxx-O)]2, Xxx = Gly (1), Ala (2). Each compound was structurally elucidated and shown to be C2 symmetric. Compound 1 displays a near-perfect rectangle shape with rhenium and α-carbon atoms at the corners.

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