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Elena Serrano, Tatiana Soler and Esteban P. Urriolabeitia Synthesis, Structure, and Reactivity of Pd Complexes with Mixed P,S-Bis(ylide), Ylide–Sulfide, and Ylide–Methanide Ligands European Journal of Inorganic Chemistry 2013

Version of Record online: 12 FEB 2013 | DOI: 10.1002/ejic.201201465

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The reactivity of phosphorus–sulfur bis(ylides), ylide–sulfides, and ylide–methanides toward PdII has been studied. Neutral bis(ylides) bond as C,C-chelates diastereoselectively [meso form (RS/SR)] owing to a combination of 1,4-P···O and 1,4-S···O interactions and 1,6-CH···O hydrogen bonds. The anionic ylide–methanide also bonds selectively as a C,C-chelate, but in the D,L form (RR/SS).

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