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Martin Bette, Jürgen Schmidt and Dirk Steinborn Diacetylplatinum(II) and -platinum(IV) Complexes Bearing κ2- and κ3-Coordinated Tris(pyrazolyl)methane Ligands: Investigations on the Synthesis, Fluxionality, and Reactivity in Relation to the Substitution Pattern of the Ligands European Journal of Inorganic Chemistry 2013

Version of Record online: 8 MAR 2013 | DOI: 10.1002/ejic.201201468

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The influence of the substitution pattern of tris(pyrazolyl)methane ligands (pz versus 3,5-Me2pz) on the reactivity and fluxionality of diacetylplatinum(II) complexes as well as the synthesis of diacetyl(alkynyl)platinum(IV) complexes by means of oxidative addition reactions using alkynyliodine(III) reagents is described.

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