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Javier Mazuela, Oscar Pàmies and Montserrat Diéguez Enantioselective Ir-Catalyzed Hydrogenation of Minimally Functionalized Olefins Using Pyranoside Phosphinite-Oxazoline Ligands European Journal of Inorganic Chemistry 2013

Version of Record online: 21 FEB 2013 | DOI: 10.1002/ejic.201201485

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Pyranoside phosphinite-oxazoline ligands were successfully applied in the asymmetric Ir-catalyzed hydrogenation of a wide range of minimally functionalized olefins (ee up to 99 %). The introduction of a bulky ortho-tolyl phosphinite moiety was crucial to achieving the highest enantioselectivities with some of the most challenging substrate types.

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