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Sabrina Kronig, Peter G. Jones and Matthias Tamm Preparation of 2-Alkylidene-Substituted 1,3,4,5-Tetramethylimidazolines and Their Reactivity Towards RhI Complexes and B(C6F5)3 European Journal of Inorganic Chemistry 2013

Article first published online: 26 FEB 2013 | DOI: 10.1002/ejic.201201516

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Several 1,3,4,5-tetramethyl-2-alkylideneimidazolines were prepared, and their reactivity towards RhI complexes and B(C6F5) was studied. Depending on the alkylidene substituent, diverse reaction patterns were observed that involved not only coordination through the exocyclic carbon atom, but also formation of unusual adducts as illustrated for the CPh2 derivative and its reaction with B(C6F5)3.

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