Ashis Bhattacharjee, Madhusudan Roy, Vadim Ksenofontov, Jonathan A. Kitchen, Sally Brooker and Philipp Gütlich Pressure Effect Studies on the Spin-Transition Behavior of a Dinuclear Iron(II) Compound European Journal of Inorganic Chemistry 2013
The spin-transition behavior of a dinuclear FeII compound is studied to explore how increased pressure favors the stabilization of the system through a transition from the [HS–HS] to the [HS–LS] state with no evidence of the [LS–LS] state even at the highest applied pressure (HS = high spin, LS = low spin). The origin of the spin transition lies with the rigidness of the bridging ligand.
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