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Erin Sheepwash, Kai Zhou, Rosario Scopelliti and Kay Severin Self-Assembly of Arylboronate Esters with Pyridyl Side Chains European Journal of Inorganic Chemistry 2013

Article first published online: 13 MAR 2013 | DOI: 10.1002/ejic.201300084

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Dioxaborinanes and benzodioxaboroles containing pyridyl side chains were synthesized. The boronate esters can aggregate through dative boron–nitrogen bonds to give trimeric and tetrameric macrocycles as well as polymeric structures. The assembly process was found to depend to a large extent on electronic effects.

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