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Aleš Korotvička, Ivan Šnajdr, Petr Štěpnička, Ivana Císařová, Zbyněk Janoušek and Martin Kotora Synthesis, Molecular Structure, and Electrochemistry of 1-Ferrocenyl-1,2-dicarba-closo-dodecaboranes European Journal of Inorganic Chemistry 2013

Version of Record online: 9 APR 2013 | DOI: 10.1002/ejic.201300110

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6,9-(Me2S)2-arachno-B10H12 reacts smoothly with ferrocenyl alkynes bearing simple and functional substituents at the triple bond to afford the respective 1-ferrocenyl-1,2-dicarba-closo-dodecaboranes in good yields. The compounds were structurally characterized by spectroscopic methods, X-ray crystallography, and voltammetric techniques.

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