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Nedaossadat Mirzadeh, Martin Bennett, Jörg Wagler, Erik Wächtler, Birgit Gerke, Rainer Pöttgen and Suresh Bhargava Dichotomy between Palladium(II)–Tin(II) and Palladium(0)–Tin(IV) in Complexes of a Sn,As-Based Chelate Ligand European Journal of Inorganic Chemistry 2013

Version of Record online: 19 MAR 2013 | DOI: 10.1002/ejic.201300115

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Metal oxidation states in Pd–Sn compounds are a continuing puzzle. A novel dinuclear Pd–Sn bonded complex is reported, in which the interaction of the formally tin(II)-based ligand, [2-MeBrSnC6F4AsPh2], with palladium appears to be best described as PdI–SnIII or Pd0–SnIV.

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