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Benjamin S. Gutrath, Ulli Englert, Yutian Wang and Ulrich Simon A Missing Link in Undecagold Cluster Chemistry: Single-Crystal X-ray Analysis of [Au11(PPh3)7Cl3] European Journal of Inorganic Chemistry 2013

Article first published online: 19 MAR 2013 | DOI: 10.1002/ejic.201300148

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Got you! Since 1966, reduction of [Au(PPh3)Cl] in ethanol represented the easiest large-scale synthesis of undecagold and gold clusters. However, the full molecular structure of this Au11 cluster remained unclear, and several formulae were published. Now, structure elucidation was successful, which is thought to bring added value from past publications and important impact to new investigations.

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