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Yan Suffren, Isabelle Gautier-Luneau, Céline Darie, Céline Goujon, Murielle Legendre and Olivier Leynaud First Evidence of a Phase Transition in a High-Pressure Metal Iodate: Structural and Thermal Studies of AgIO3 Polymorphs European Journal of Inorganic Chemistry 2013

Version of Record online: 31 MAY 2013 | DOI: 10.1002/ejic.201300191

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β-AgIO3 is the first iodate phase obtained under high pressure. The reconstructive phase transition from the α-AgIO3 acentric phase to the dense β-AgIO3 centric phase is an endothermic transformation that occurs at 260 °C at 2.7 GPa.

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