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Anthony Schultz, Xiaopeng Li, Charles N. Moorefield, Chrys Wesdemiotis and George R. Newkome Self-Assembly and Characterization of 3D Metallamacrocycles: A Study of Supramolecular Constitutional Isomers European Journal of Inorganic Chemistry 2013

Article first published online: 3 APR 2013 | DOI: 10.1002/ejic.201300286

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Two metallamacromolecular constitutional isomeric pairs were self-assembled based on <tpy-MII-tpy> connectivity. These isomers were characterized by 1H NMR spectroscopy and mass spectrometry (ESI-travelling wave ion mobility), which revealed significant structural differences. Molecular modeling was utilized to aid in characterization.

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