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Gilles Schnee, Christophe Fliedel, Teresa Avilés and Samuel Dagorne Neutral and Cationic N-Heterocyclic Carbene Zinc Adducts and the BnOH/Zn(C6F5)2 Binary Mixture – Characterization and Use in the Ring-Opening Polymerization of β-Butyrolactone, Lactide, and Trimethylene Carbonate European Journal of Inorganic Chemistry 2013

Version of Record online: 4 JUN 2013 | DOI: 10.1002/ejic.201300292

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A variety of new N-heterocyclic carbene (NHC) organozinc adducts are synthesized and characterized, among which are the first examples of NHC-stabilized zinc organocations. The NHC–Zn(C6F5)2 adducts and BnOH/Zn(C6F5)2 are effective ring-opening polymerization (ROP) initiators of cyclic esters/carbonates under mild conditions.

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