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Kai Altenburger, Julia Semmler, Perdita Arndt, Anke Spannenberg, Matthias J. Meel, Alexander Villinger, Wolfram W. Seidel and Uwe Rosenthal Examples of Different Reactions of Benzylsulfanyl-Substituted Alkynes with Selected Complexes of TiII and CoI European Journal of Inorganic Chemistry 2013

Article first published online: 17 JUN 2013 | DOI: 10.1002/ejic.201300312

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Sulfur-substituted alkynes show contrasting behaviour in their reactions with TiII and CoI. Whereas the TiII centre in the titanocene η2-alkyne complex effects a cleavage of the alkyne Csp–S bond concomitant with C–C coupling, CoI in the [Co(triphos)] η2-alkyne complex leads to loss of the benzyl groups to give either a heterobimetallic Co/Ru acetylene dithiolate complex or a dithiolene complex.

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