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Zhengguo Lin, Bo Wang, Jie Cao, Baokuan Chen, Chong Xu, Xianqiang Huang, Yanxuan Fan and Changwen Hu Controlled Synthesis of Polyoxopalladates, and Their Gas-Phase Fragmentation Study by Electrospray Ionization Tandem Mass Spectrometry European Journal of Inorganic Chemistry 2013

Article first published online: 21 MAY 2013 | DOI: 10.1002/ejic.201300372

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Two polyoxopalladates {Pd12XIII} have been synthesized by using Cr3+ and In3+ ions as structural directing agents. The coordination configuration of the central metal ions influenced by their ionic radii can affect the cluster stability, as shown by their collision-induced dissociation MS/MS spectra. This approach may help us to understand the stability and dissociation of polyoxopalladates.

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