Masanari Hirahara, Akinori Shoji and Masayuki Yagi Artificial Manganese Center Models for Photosynthetic Oxygen Evolution in Photosystem II European Journal of Inorganic Chemistry 2014
To achieve artificial photosynthesis, the development of water oxidation catalysts is key. The photosynthetic oxygen evolving complex (OEC) is composed of a Mn cluster and is an excellent example of such a catalyst. Significant progress has been made in the development of Mn complexes as OEC models. The molecular aspects and activities of Mn complexes toward water oxidation catalysis are reviewed.
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