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Ting Hu and Thomas C. W. Mak Assembly of Silver–Organic Frameworks Containing Trifluoroacetate, Embedded 1,5-Hexadiyne-1,6-diide, and Ancillary Nitrogen-Donor Ligands European Journal of Inorganic Chemistry 2013

Version of Record online: 17 SEP 2013 | DOI: 10.1002/ejic.201300798

Thumbnail image of graphical abstract

Ten new silver–organic frameworks containing trifluoroacetate, 1,5-hexadiyne-1,6-diide (C≡CCH2CH2C≡C, C6H42–), and various types of ancillary N-donors have been assembled with the multinuclear metal–ligand supramolecular synthon C6H4⊂Agn (n = 7, 8, 9), in which the C6H42– ligand has a gauche configuration.

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