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Shuli Chen, Jun Xuan Chiew, Sumod A. Pullarkat, Yongxin Li and Pak-Hing Leung Stability and Reactivity of Cyclometallated Naphthylamine Complexes in Pd–C Bond Insertion Reactions with Coordinated Alkynylphosphanes European Journal of Inorganic Chemistry 2013

Version of Record online: 17 SEP 2013 | DOI: 10.1002/ejic.201300834

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The asymmetric monoinsertion of PhP(C≡CPh)2 coordinated to a cyclometallated N,N-dimethyl naphthyl/benzylamine template into the Pd–C bonds of N,N-dimethylnaphthylamine palladacycles has been demonstrated for the synthesis of a variety of new P-stereogenic homo- or heterodimetallic complexes.

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