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Vladislav V. Krisyuk, Iraida A. Baidina, Tamara V. Basova, Lyubov G. Bulusheva and Igor K. Igumenov Self-Assembly of Coordination Polymers from Volatile PdII and PbII β-Diketonate Derivatives through Metallophilic Interactions European Journal of Inorganic Chemistry 2013

Version of Record online: 2 OCT 2013 | DOI: 10.1002/ejic.201300876

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Dimetallic coordination polymers based on neutral metal β-diketonate derivatives can form as a result of attractive metal–metal interactions. Structural evidence of the formation of PdII···PbII metallophilic interactions in a series of similar compounds is reported. The steric and electronic factors of chelate ligands can be used to design the architecture of these new coordination polymers.

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