Sebastian Schäfer, Heiko Bauer, Julia Becker, Yu Sun and Helmut Sitzmann Cyclononatetraenyl-Indenyl Transformation and a Zirconium(III) Trimer from Bulky Alkylcyclopentadienylzirconium Chlorides European Journal of Inorganic Chemistry 2013
During a search for cyclononatetraenylzirconium complexes, cyclononatetraenide lost two hydrogen atoms and formed indenyl complexes with alkylcyclopentadienylzirconium(IV) trichlorides. Another starting compound was obtained by potassium reduction of [Cp″′ZrCl3]. The trimer [Cp″′ZrCl2]3 shows bonding Zr···Zr interactions of 3.384 Å.
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