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Benjamin Gutschank, Melike Bayram, Stephan Schulz, Dieter Bläser and Christoph Wölper Heterobimetallic Metal–Amidinate Complexes by Stepwise Metalation of Methanetrisamidines European Journal of Inorganic Chemistry 2013

Version of Record online: 19 SEP 2013 | DOI: 10.1002/ejic.201300939

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Methanetrisamidines can be two- and four-fold metalated by different metal organic complexes to form di- and tetranuclear homometallic complexes, respectively. Moreover, the different acidity of the N–H groups also allows the stepwise deprotonation by different organometallic reagents with the subsequent formation of heterobimetallic complexes.

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