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Fabio Marchetti, Guido Pampaloni, Calogero Pinzino and Stefano Zacchini Stable [M2F11]– (M = Nb, Ta) Salts of Protonated 1,3-Dimethoxybenzene European Journal of Inorganic Chemistry 2013

Version of Record online: 2 OCT 2013 | DOI: 10.1002/ejic.201300961

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The unusual characteristics of MF5 (M = Nb, Ta), i.e. oxidising behaviour and capability of generating inert anion derivatives, have been exploited for the preparation of [M2F11] salts of protonated 1,3-dimethoxybenzene. The salts are stable at room temperature under an inert atmosphere both in the solid-state and in chlorinated solvents.

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