Michael Teltewskoi, Sabrina I. Kalläne, Thomas Braun and Roy Herrmann Synthesis of Rhodium(I) Boryl Complexes: Catalytic N–H Activation of Anilines and Ammonia European Journal of Inorganic Chemistry 2013
Sixteen-electron RhI boryl complexes are synthesized and used for N–H bond activation reactions of anilines. The treatment of [Rh(Bpin)(PEt3)3] (HBpin = pinacolborane) with NH3 yields the diborylamine HN(Bpin)2. The stoichiometric conversion led to the development of a new catalytic process, and [Rh(Bpin)(PEt3)3] is used as a catalyst to convert NH3 and B2pin2 into HN(Bpin)2 at room temperature.
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