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Dongren Wang, Jörg Unold, Martina Bubrin, Iris Elser, Wolfgang Frey, Wolfgang Kaim, Guangjuan Xu and Michael R. Buchmeiser Ruthenium–Triazene Complexes as Latent Catalysts for UV-Induced ROMP European Journal of Inorganic Chemistry 2013

Version of Record online: 24 SEP 2013 | DOI: 10.1002/ejic.201301048

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Three novel complexes, RuX2(IMesH2)[N,N-diethyl-N′-(2-benzylidene)triazene] [IMesH2 = 1,3-dimesitylimidazolin-2-ylidene; X = Cl (2), CF3COO (3), C6F5COO (4)] are used in the UV-induced ring-opening metathesis polymerization (ROMP) of cis-cyclooctene and dicyclopentadiene. The photoactivity of 24 decreases with increasing electron-withdrawing character and with decreasing pKa of the X groups.

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