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Yasuchika Hasegawa, Tomoki Ohkubo, Takayuki Nakanishi, Atsushi Kobayashi, Masako Kato, Tomohiro Seki, Hajime Ito and Koji Fushimi Effect of Ligand Polarization on Asymmetric Structural Formation for Strongly Luminescent Lanthanide Complexes European Journal of Inorganic Chemistry 2013

Version of Record online: 8 OCT 2013 | DOI: 10.1002/ejic.201301102

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EuIII complexes with three hexafluoroacetylacetonate and two monodentate phosphine oxide ligands exhibit characteristic square-antiprismatic or trigonal-dodecahedral structures depending on the ligand polarization. Ligands with large dipole moments result in characteristic dodecahedron structures and markedly high emission quantum yields (72 % in [D6]acetone, 85 % in the solid state).

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