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Duncan Carmichael, Xavier-Frédéric le Goff and Eric Muller Oligo(metallocene)s Containing Keto-Bridged Phospholyl Rings European Journal of Inorganic Chemistry 2014

Version of Record online: 19 DEC 2013 | DOI: 10.1002/ejic.201301144

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The homologation of a 2,5-diester substituted phosphametallocene into a 2′,5-diester substituted triphosphametallocene array is presented. The high stereochemical selectivity for the (±)-(R*,R*) configured triphosphametallocene product is shown to result from an autotemplation of the reaction pathway.

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