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Jörg Weiß, Katharina Sinner, Johannes A. Baus, Christian Burschka and Reinhold Tacke Neutral Hexacoordinate Silicon(IV) Complexes with a SiO4NC or SiO3N2C Skeleton and Neutral Pentacoordinate Silicon(IV) Complexes Containing a Trianionic Tetradentate O,N,O,O Ligand European Journal of Inorganic Chemistry 2014

Version of Record online: 18 DEC 2013 | DOI: 10.1002/ejic.201301185

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A series of hexacoordinate silicon(IV) complexes and two pentacoordinate silicon(IV) complexes was synthesized and structurally characterized. The hexacoordinate compounds contain a tridentate dianionic O,N,O or N,N,O ligand, a phenyl ligand, and a symmetrically substituted acetylacetonato ligand of the type RC(O)–CH=C(OSiMe3)R (R = Me, Ph, CF3). The pentacoordinate complexes contain a tetradentate trianionic O,N,O,O ligand and a phenyl ligand.

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