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Manuel Joas, Thomas M. Klapötke and Norbert Szimhardt Photosensitive Metal(II) Perchlorates with 1,2-Bis[5-(1-methylhydrazinyl)tetrazol-1-yl]ethane as Ligand: Synthesis, Characterization and Laser Ignition European Journal of Inorganic Chemistry 2014

Article first published online: 12 DEC 2013 | DOI: 10.1002/ejic.201301283

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Three perchlorate-containing metal complexes with 1,2-bis[5-(1-methylhydrazinyl)tetrazol-1-yl]ethane as ligand are presented as laser-sensitive explosives. Their preparation and characterization with a focus on their energetic properties is discussed. The figure shows the moment of detonation after laser ignition (of a confined sample in a glass tube) and the crystal structure of the copper(II) complex.

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