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Almudena García-Fernández, Josefina Díez, M. Pilar Gamasa and Elena Lastra 1,3-Dipolar Cycloaddition Reactions of Neutral and Cationic Hydridotris(pyrazolyl)borate–Ruthenium(II) Azido Complexes European Journal of Inorganic Chemistry 2014

Article first published online: 20 DEC 2013 | DOI: 10.1002/ejic.201301298

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Azido half-sandwich ruthenium(II) complexes have been synthesized and their 1,3-dipolar cycloaddition reactions with tetracyanoethylene and with activated alkynes, dimethyl acetylenedicarboxylate (DMAD) and diethyl acetylenedicarboxylate (DEAD), have been studied. Complexes containing tetrazolate and trizolate ligands were obtained, respectively.

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