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Denis S. Salnikov, Polina N. Kucherenko, Ilia A. Dereven'kov, Sergei V. Makarov and Rudi van Eldik Kinetics and Mechanism of the Reaction of Hydrogen Sulfide with Cobalamin in Aqueous Solution European Journal of Inorganic Chemistry 2014

Article first published online: 2 JAN 2014 | DOI: 10.1002/ejic.201301340

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The reaction of aquacobalamin with hydrogen sulfide proceeds in three steps: formation of a complex between aquacobalamin and hydrogen sulfide, inner-sphere electron transfer, and addition of a second molecule of hydrogen sulfide to the reduced cobalamin. The main reaction products are different in alkaline and acidic media.

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