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Cornelis G. J. Tazelaar, Volodymyr Lyaskovskyy, Ilana M. van Doorn, Xander Schaapkens, Martin Lutz, Andreas W. Ehlers, J. Chris Slootweg and Koop Lammertsma Tris(pyrazolyl)phosphine Oxide and Tris(triazolyl)phosphine Oxide Scorpion Ligands European Journal of Inorganic Chemistry 2014

Article first published online: 17 DEC 2013 | DOI: 10.1002/ejic.201301352

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Phosphorus-centered scorpion ligands OP(Pz)3 (Pz = pyrazolyl) and OP(Tz)3 (Ty = triazolyl) were found to be similar to their carbon analogues [HC(Pz)3 and HC(Tz)3], also on CuI complexation, according to DFT calculations. Experimentally, the two OP-capped ligands act differently from each other, giving the expected monomer for the CuI complex of OP(Pz)3, but a dimer for that of OP(Tz)3.

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