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Xu-Miao Zhou, Wei Chen and Yu-Fei Song Superhydrophobic Polyoxometalate/Calixarene Inorganic–Organic Hybrid Materials with Highly Efficient Desulfurization Ability European Journal of Inorganic Chemistry 2014

Version of Record online: 17 JAN 2014 | DOI: 10.1002/ejic.201301407

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Ion-exchange of compounds with the formula [C44H56O4·2C4H6N2(CH2)n]·2Br by Na9EuW10O36·32H2O results in the formation of inorganic–organic hybrid materials, which exhibit superhydrophobicity with a contact angle of >139°. The application of these hybrids in extractive catalytic oxidative desulfurization indicates that they are highly efficient and selective heterogeneous catalytic systems.

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