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Timo Huxel, Selina Leone, Yanhua Lan, Serhiy Demeshko and Julia Klingele 2-Amino-4-(2-pyridyl)thiazole as Chelating Ligand: A Dinuclear Oxido-Bridged Ferric Complex and Mononuclear 3d Metal Complexes European Journal of Inorganic Chemistry 2014

Article first published online: 22 MAY 2014 | DOI: 10.1002/ejic.201400041

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On treatment with Fe(BF4)2·6H2O, the 2-amino-4-(2-pyridyl)thiazole ligand forms rare examples of either an oxido-bridged ferric complex with F co-ligands or a mononuclear difluorido ferric complex with FeF2N4 coordination, depending on the reaction conditions.

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