Julie Jung, Tamyris T. da Cunha, Boris Le Guennic, Fabrice Pointillart, Cynthia L. M. Pereira, Javier Luzon, Stéphane Golhen, Olivier Cador, Olivier Maury and Lahcène Ouahab Magnetic Studies of Redox-Active Tetrathiafulvalene-Based Complexes: Dysprosium vs. Ytterbium Analogues European Journal of Inorganic Chemistry 2014
The crystal-field energy splitting of the ground-state multiplets of the complexes Dy and Yb was evaluated, and they demonstrate Ising and non-Ising character. Both anisotropy axis directions for the MJ ground states were determined in agreement with the oblate and prolate electronic distribution for DyIII and YbIII ions. This results in SMM and non-SMM behaviour for Dy and Yb, respectively.
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