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Manabu Ishikawa, Yoshiaki Nakano, Mikio Uruichi, Akihiro Otsuka, Kyuya Yakushi and Hideki Yamochi Structural and Physical Properties of (EDO-TTF-Cl)2XF6 (X = As, Sb): Geometrical Aspects for Monosubstituted EDO-TTF (EDO-TTF = 4,5-ethylenedioxytetrathiafulvalene) European Journal of Inorganic Chemistry 2014

Article first published online: 24 APR 2014 | DOI: 10.1002/ejic.201400128

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The semiconducting and metallic compounds (EDO-TTF-Cl)2XF6 (X = As and Sb, respectively) were obtained. Their properties are well correlated with their degree of intracolumnar dimerization. The in-plane intermolecular displacements in the stacking columns are the key parameters to understand the chemical pressure.

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