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Tatiana G. Prokhorova, Lev I. Buravov, Eduard B. Yagubskii, Leokadiya V. Zorina, Sergey V. Simonov, Rimma P. Shibaeva and Vladimir N. Zverev Metallic Bi- and Monolayered Radical Cation Salts Based on Bis(ethylenedithio)­tetrathiafulvalene (BEDT-TTF) with the Tris(oxalato)gallate Anion European Journal of Inorganic Chemistry 2014

Version of Record online: 9 APR 2014 | DOI: 10.1002/ejic.201400132

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Bilayered and monolayered metallic radical cation salts based on bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) with the [GaIII(C2O4)3]3–· anion have been prepared and investigated. Metallic α and nonmetallic “pseudo-κ” layers of BEDT-TTF alternate in the structure of the bilayered salt, whereas the conducting layers in the monolayered salt have only metallic β″-type packing.

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