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Verónica Gómez, Jordi Benet-Buchholz, Eddy Martin and José Ramón Galán-Mascarós Architectures in Copper Metal–Organic Frameworks from 4-Substituted Anionic 1,2,4-Triazoles European Journal of Inorganic Chemistry 2014

Article first published online: 3 JUN 2014 | DOI: 10.1002/ejic.201402019

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Three new Cu2+ coordination polymers have been synthesized with anionic 4-substituted 1,2,4-triazole derivatives under hydrothermal conditions. These compounds show different structural dimensionality: compounds 1 and 2 form layers, whereas compound 3 is a one-dimensional system. The magnetic behavior is dominated by strong antiferromagnetic exchange promoted by hydroxo and triazole bridges.

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