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Rim Makhoul, Yuki Kumamoto, Akira Miyazaki, Frédéric Justaud, Frédéric Gendron, Jean-François Halet, Jean-René Hamon and Claude Lapinte Synthesis and Properties of a Mixed-Valence Compound with Single-Step Tunneling and Multiple-Step Hopping Behavior European Journal of Inorganic Chemistry 2014

Version of Record online: 19 MAY 2014 | DOI: 10.1002/ejic.201402022

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The complex trans-[Cp*(dppe)Fe–C≡C–TTFMe2–C≡C–Fe(dppe)Cp*][PF6] [Cp* = η5-C5Me5, dppe = 1,2-bis(diphenylphosphanyl)ethane, TTF = tetrathiafulvalene] is a class II mixed-valence compound in which the spin density varies with the respective orientation of the metal termini. Intramolecular electron transfer occurs through single-step tunneling and multiple-step hopping mechanisms.

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