Samia Benmansour, Eugenio Coronado, Carlos Giménez-Saiz, Carlos J. Gómez-García and Carola Rößer Metallic Charge-Transfer Salts of Bis(ethylenedithio)tetrathiafulvalene with Paramagnetic Tetrachloro(oxalato)rhenate(IV) and Tris(chloranilato)ferrate(III) Anions European Journal of Inorganic Chemistry 2014
Three new paramagnetic molecular conductors have been prepared with the magnetic anions [ReCl4(C2O4)]2– and [Fe(C6O4Cl2)3]3–. ET[ReCl4(C2O4)] [ET = bis(ethylenedithio)tetrathiafulvalene] is a semiconductor that contains ET2+ dications. ET4[ReCl4(C2O4)] is metallic down to 110 K. ET6[Fe(C6O4Cl2)3] has high conductivity and is the first radical salt with a tris(anilato)metalate anion.
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