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Nelson W. Attandoh, Stephen O. Ojwach and Orde Q. Munro (Benzimidazolylmethyl)amine ZnII and CuII Carboxylate Complexes: Structural, Mechanistic and Kinetic Studies of Polymerisation Reactions of ϵ-Caprolactone European Journal of Inorganic Chemistry 2014

Version of Record online: 28 MAY 2014 | DOI: 10.1002/ejic.201402049

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The bimetallic and monometallic (benzimidazolylmethyl)amine ZnII and CuII carboxylate complexes form active catalysts for the ring-opening polymerisation of ϵ-caprolactone. The polymerisation reactions follow pseudo first-order kinetics and occur through an activated-monomer mechanism.

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