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Wai-Man Cheung, Wai-Hang Chiu, Herman H. Y. Sung, Ian D. Williams and Wa-Hung Leung Oxidative Addition of Rhodium Complexes Containing a Dithioimidodiphosphinate Ligand: Facile Reductive Elimination of Methyl Iodide from a Tetranuclear Rhodium Sulfido Cluster European Journal of Inorganic Chemistry 2014

Version of Record online: 22 MAY 2014 | DOI: 10.1002/ejic.201402080

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The RhIII3RhI sulfido cluster with dithioimidodiphosphinate ligands undergoes facile reductive elimination of methyl iodide in the absence of an added ligand, thus demonstrating the importance of the cooperative effect of neighboring metals and sulfur ligands in the oxidative addition/reductive elimination of metal complexes.

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