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Jing Zhang, Yaping Ou, Meng Xu, Chaofang Sun, Jun Yin, Guang-Ao Yu and Sheng Hua Liu Synthesis and Characterization of Dibenzoheterocycle-Bridged Dinuclear Ruthenium Alkynyl and Vinyl Complexes European Journal of Inorganic Chemistry 2014

Article first published online: 26 MAY 2014 | DOI: 10.1002/ejic.201402106

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A series of dinuclear ruthenium alkynyl and vinyl complexes are synthesized, and their properties are investigated by electrochemical and spectroelectrochemical methods. The experimental results consistently demonstrate that the bridging ligands strongly contribute to the oxidation processes, and DFT calculations further confirm the redox noninnocence of the bridging ligands.

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