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Sanjit Nayak, Ghenadie Novitchi, Małgorzata Hołyńska and Stefanie Dehnen Two Heterometallic Ionic Compounds with Isolated [3d] and [4f] Complex Units: Field-Induced Single-Ion Magnet (SIM) Behavior Observed from a Mononuclear Dysprosium(III) Complex European Journal of Inorganic Chemistry 2014

Version of Record online: 3 JUN 2014 | DOI: 10.1002/ejic.201402114

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Two new 3d-4f compounds were synthesized as the combination of two complex cores with a general formula of [Fe3O][Ln]. The units are connected through hydrogen bond interactions. The anionic [Ln] units are encapsulated in cationic [Fe3O] aggregates. The [Fe3O][Dy] compound shows slow relaxation of magnetization at low temperature, which makes it a field-induced single-ion magnet.

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