Sandesh Pai, Krzysztof Radacki and Ulrich Schatzschneider Sonogashira, CuAAC, and Oxime Ligations for the Synthesis of MnI Tricarbonyl PhotoCORM Peptide Conjugates European Journal of Inorganic Chemistry 2014
Appropriately terminated peptides have been conjugated to MnI(CO)3 complexes bearing a modified bpea ligand through either a triazole or oxime linker by bioorthogonal coupling. Both the coupling methodology and bpea ligand structure are vital for successful conjugation. The peptide conjugates showed potential for the targeted delivery of CO to biological systems.
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