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Anatoliy Marchenko, Georgyi Koidan, Anastasiya Hurieva, Olena Kurpiieva, Yurii Vlasenko, Alexander B. Rozhenko and Aleksandr Kostyuk Stable N-Phosphanyl Acyclic Diaminocarbenes European Journal of Inorganic Chemistry 2014

Article first published online: 12 JUN 2014 | DOI: 10.1002/ejic.201402166

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The deprotonation of PIII N-substituted formamidinium salts afforded a new type of stable acyclic N-phosphanyl-diaminocarbene. The carbenes possess an optimal substitution pattern, deviations from which make them unstable. They transform into C-phosphanylformamidines by a N,C-phosphorus shift, which was studied by quantum chemistry calculations.

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