Fabrice Pointillart, Stéphane Golhen, Olivier Cador and Lahcène Ouahab Slow Magnetic Relaxation in a Redox-Active Tetrathiafulvalene-Based Ferromagnetic Dysprosium Complex European Journal of Inorganic Chemistry 2014
The dinuclear coordination complex [Dy(tta)2(L1)(L2)]2·2(CH2Cl2) [tta = 2-thenoyltrifluoroacetonate, L1 and L2 = tetrathiafulvalene (TTF) ligands] shows significant ferromagnetic interactions between both DyIII ions. Owing to the two different TTF ligands, the molecule is a multiredox system. It also displays single-molecule magnetic behaviour with the Ising ground state MJ = ±15/2.
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